|標題:||Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy|
Department of Electrophysics
|摘要:||A transition state (TS) during Raman triggered oxidation of chloroform was directly observed by ultrafast spectroscopy using broadband visible sub-5 fs pulses. Changes in the molecular structures including the TSs along the reaction pathways were detected by the time-dependent instantaneous frequencies of vibrational modes. The Raman triggered oxidation of chloroform was found to be initiated by the excitation of vibrational levels through stimulated Raman processes involving the ground-state chloroform oxygen complex. (C) 2008 Published by Elsevier B.V.|
|期刊:||CHEMICAL PHYSICS LETTERS|
|Appears in Collections:||Articles|
Files in This Item:
If it is a zip file, please download the file and unzip it, then open index.html in a browser to view the full text content.