Title: Dual-mode recognition of transition metal ions by bis-triazoles chained pyrenes
Authors: Hung, Hao-Chih
Cheng, Chi-Wen
Ho, I-Ting
Chung, Wen-Sheng
應用化學系
Department of Applied Chemistry
Issue Date: 21-Jan-2009
Abstract: Fluorescent chemosensors 7-10, with variable methylene chain length as spacers between the two triazole methyl ether units, have been synthesized under 'Click' condition, where the bistriazoles are used as the metal ion binding sites and the pyrenes as the fluorophores. Compound 10, having the longest methylene chain among 7-10, shows monomer and excimer fluorescence quenching in acetonitrile toward Ni(2+), Pb(2+), Cu(2+), Hg(2+), and Cr(3+) ions, however, it shows an enhanced monomer but a decreased excimer emission when complexed with Cd(2+) and Zn(2+) ions. (C) 2008 Elsevier Ltd. All rights reserved.
URI: http://dx.doi.org/10.1016/j.tetlet.2008.10.147
http://hdl.handle.net/11536/7729
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.10.147
Journal: TETRAHEDRON LETTERS
Volume: 50
Issue: 3
Begin Page: 302
End Page: 305
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