Title: Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions
Authors: Chung, WS
Ho, CC
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
Issue Date: 7-Feb-1997
Abstract: When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 +/- 0.01) rather than exhibiting the expected Paterno-Buchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.
URI: http://dx.doi.org/10.1039/a607415d
http://hdl.handle.net/11536/727
ISSN: 1359-7345
DOI: 10.1039/a607415d
Journal: CHEMICAL COMMUNICATIONS
Volume: 
Issue: 3
Begin Page: 317
End Page: 318
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  1. A1997WJ50700034.pdf