標題: Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions
作者: Chung, WS
Ho, CC
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
公開日期: 7-二月-1997
摘要: When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 +/- 0.01) rather than exhibiting the expected Paterno-Buchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.
URI: http://dx.doi.org/10.1039/a607415d
http://hdl.handle.net/11536/727
ISSN: 1359-7345
DOI: 10.1039/a607415d
期刊: CHEMICAL COMMUNICATIONS
Volume: 
Issue: 3
起始頁: 317
結束頁: 318
顯示於類別:期刊論文


文件中的檔案:

  1. A1997WJ50700034.pdf