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dc.contributor.authorTu, Cheng-Weien_US
dc.contributor.authorKuo, Shiao-Weien_US
dc.contributor.authorChang, Feng-Chihen_US
dc.date.accessioned2014-12-08T15:09:17Z-
dc.date.available2014-12-08T15:09:17Z-
dc.date.issued2009-06-19en_US
dc.identifier.issn0032-3861en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.polymer.2009.04.034en_US
dc.identifier.urihttp://hdl.handle.net/11536/7098-
dc.description.abstractA well-defined poly(ethylene oxide-block-N-isopropylacrylamide) (PEO-b-PNIPAM) diblock copolymer was synthesized by atom transfer radical polymerization and formed the inclusion complexes (ICs) after selective threading of the PEO segment of the block copolymer through the cavities of alpha-cyclodextrin (alpha-CD) units. The formation of the alpha-CD/PEO ICs between alpha-CD and PEO segment of the PEO-b-PNIPAM transformed the system from its original random coil conformation into a rod/coil-like structure. The stacking of the alpha-CD/PEO ICs and phase separation within the alpha-CD/PEO-b-PNIPAM IC resulted in the self-assembly of long-range-ordered lamellar structure exhibiting alternating layers of (i) alpha-CD/PEO ICs with hexagonally packed plates and (ii) amorphous phase of unincluded PEO/PNIPAM with brush conformation. (C) 2009 Elsevier Ltd. All rights reserved.en_US
dc.language.isoen_USen_US
dc.subjectCyclodextrinen_US
dc.subjectInclusion complexesen_US
dc.subjectBlock copolymeren_US
dc.titleSupramolecular self-assembly through inclusion complex formation between poly(ethylene oxide-b-N-isopropylacrylamide) block copolymer and alpha-cyclodextrinen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.polymer.2009.04.034en_US
dc.identifier.journalPOLYMERen_US
dc.citation.volume50en_US
dc.citation.issue13en_US
dc.citation.spage2958en_US
dc.citation.epage2966en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000267415600028-
dc.citation.woscount25-
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