|標題:||A mild and general method for preparation of alpha-glycosyl chlorides|
Mong, Kwok-Kong T.
Department of Applied Chemistry
|摘要:||A mild and efficient chlorination method for production of glycosyl chlorides is first described which employs inexpensive trichlorotriazine (TCT) and DMF as a chlorination reagent and is compatible with typical acid-labile hydroxyl protecting functions. The scope and limitations, reaction mechanism and its application in the sequential glycosylations are discussed. (C) 2009 Elsevier Ltd. All rights reserved.|
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