標題: Colorimetric sensing of Cu(II): Cu(II) induced deprotonation of an amide responsible for color changes
作者: Wu, Shu-Pao
Du, Kun-Ju
Sung, Yi-Ming
應用化學系
Department of Applied Chemistry
公開日期: 2010
摘要: 9,10-Anthraquinone-based chemosensor 1 indicates the presence of Cu(II) ions among other transition metal ions with high selectivity by a color change from yellow to dark red. Chemosensor 2 shows binding toward Cu(II), Ni(II) and Co(II) with color changes from yellow to dark red, red and pale green, respectively. Especially, Co(II) binding with chemosensor 2 causes significantly green fluorescence. On addition of Cu(II), 1 and 2 exhibit 76 and 80 nm red shifts in absorption wavelength (pH 7.0). The effect on pH by the formation of these 1-Cu(II) and 2-Cu(II) complexes was determined by UV-vis spectroscopic pH titration. In the pH range of 6-7.5, a maximum absorption was observed at 473 nm and exhibited the formation of deprotonated 1-Cu(II) and 2-Cu(II) complexes.
URI: http://hdl.handle.net/11536/6096
http://dx.doi.org/10.1039/b925898a
ISSN: 1477-9226
DOI: 10.1039/b925898a
期刊: DALTON TRANSACTIONS
Volume: 39
Issue: 18
起始頁: 4363
結束頁: 4368
顯示於類別:期刊論文


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