標題: Structural amendment and stereoselective synthesis of mutisianthol
作者: Ho, TL
Lee, KY
Chen, CK
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
公開日期: 16-五月-1997
摘要: cis-1-(5-Acetoxy-3,6-dimethyl-1-indanyl)-2-methyl-1-propene synthesized from 3,6-dimethyl-1-indanone was found to be different from mutisianthol by spectral comparison. The presence of a high-field signal in the NMR spectrum of the final product and various intermediates, characteristic of the cis-1,3-dialkylindanes but absent in the spectrum of the natural terpene, suggests a revision of the structure of mutisianthol to the trans isomer. The trans-indane which was subsequently obtained indeed exhibits data fully agreeable with mutisianthol. A similar stereochemical revision for jungianol is also indicated.
URI: http://dx.doi.org/10.1021/jo970073+
http://hdl.handle.net/11536/534
ISSN: 0022-3263
DOI: 10.1021/jo970073+
期刊: JOURNAL OF ORGANIC CHEMISTRY
Volume: 62
Issue: 10
起始頁: 3365
結束頁: 3369
顯示於類別:期刊論文


文件中的檔案:

  1. A1997WZ55500052.pdf