Title: Structural amendment and stereoselective synthesis of mutisianthol
Authors: Ho, TL
Lee, KY
Chen, CK
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
Issue Date: 16-May-1997
Abstract: cis-1-(5-Acetoxy-3,6-dimethyl-1-indanyl)-2-methyl-1-propene synthesized from 3,6-dimethyl-1-indanone was found to be different from mutisianthol by spectral comparison. The presence of a high-field signal in the NMR spectrum of the final product and various intermediates, characteristic of the cis-1,3-dialkylindanes but absent in the spectrum of the natural terpene, suggests a revision of the structure of mutisianthol to the trans isomer. The trans-indane which was subsequently obtained indeed exhibits data fully agreeable with mutisianthol. A similar stereochemical revision for jungianol is also indicated.
URI: http://dx.doi.org/10.1021/jo970073+
http://hdl.handle.net/11536/534
ISSN: 0022-3263
DOI: 10.1021/jo970073+
Journal: JOURNAL OF ORGANIC CHEMISTRY
Volume: 62
Issue: 10
Begin Page: 3365
End Page: 3369
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