標題: CHEMORHEOLOGY ON SIMULTANEOUS IPN FORMATION OF EPOXY-RESIN AND UNSATURATED POLYESTER
作者: LIN, MS
CHANG, RJ
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
公開日期: 15-十月-1992
摘要: Study of the simultaneous interpenetrating polymer network (IPN) between diglycidyl ether of bisphenol-A (DGEBA) and unsaturated polyester (UP) was carried out at ambient temperature. Fourier transform infrared (FTIR) spectroscopy was employed to investigate the intermolecular H-bonding and functional group changes. Viscosity changes due to H-bonding and crosslinking were examined with a Brookfield viscometer. Gelation time was measured by a Techne gelation timer. Complexation between Co (II) (the promoter for UP cure) and diamine (the curing agent for DGEBA) was detected with UV-visible spectrometer. Experimental evidence revealed that intermolecular interactions were observed in systems such as DGEBA/UP, DGEBA/diamine, UP/diamine, Co (II) /diamine, DGEBA/uncured UP, and UP/uncured DGEBA. All such interactions had measurable effects on the curing behaviors for both networks, as were indicated by the viscosity changes and gelation time. The IPNs thus obtained were further characterized with rheometric dynamic spectroscopy (RDS) and differential scaning calorimetry (DSC). Partial compatibility between UP and DGEBA networks was evidenced from a main damping peak with a shoulder near glass transition temperature (T(g)) for lower UP content; while at higher UP content, only a main damping peak near T(g) was observed. DSC revealed a broad glass transition for all IPNs. The resultant IPN materials were all transparent.
URI: http://dx.doi.org/10.1002/app.1992.070460509
http://hdl.handle.net/11536/3264
ISSN: 0021-8995
DOI: 10.1002/app.1992.070460509
期刊: JOURNAL OF APPLIED POLYMER SCIENCE
Volume: 46
Issue: 5
起始頁: 815
結束頁: 827
顯示於類別:期刊論文


文件中的檔案:

  1. A1992JN12200009.pdf