標題: Protection of epoxy resin against thermo-oxidation via co-curing epoxy/resole (I)
作者: Lin, MS
Chiu, CC
應用化學系
Department of Applied Chemistry
關鍵字: thermo-oxidation;co-curing;degradation rate constants
公開日期: 2000
摘要: Co-cured materials based on 100/0, 50/50 and 0/100 weight ratios of resole/epoxy were prepared by using NaOH and 4,4'-diaminodiphenylmethane (MDA) as curing agents. Samples were spin-coated on Al plates and were subjected to accelerated aging at 150 degrees C in air for 49 days. The functional group changes during thermal oxidation were monitored with FT-IR at various times. Difference spectra were obtained by using aromatic absorption at 1608 cm(-1) as internal standard. Kinetic study was performed, and a first order of degradation was demonstrated. Experimental results revealed that the degradation rate constants for pure epoxy, 50/50 of resole/epoxy and pure resole are 9.32x10(-3), 4.29x10(-3) and 2.03x10(-3) h(-1), respectively, indicating a significant protection of epoxy against thermal oxidation via co-curing resole/epoxy. (C) 2000 Elsevier Science Ltd. All rights reserved.
URI: http://hdl.handle.net/11536/30867
http://dx.doi.org/10.1016/S0141-3910(00)00058-6
ISSN: 0141-3910
DOI: 10.1016/S0141-3910(00)00058-6
期刊: POLYMER DEGRADATION AND STABILITY
Volume: 69
Issue: 2
起始頁: 251
結束頁: 253
顯示於類別:期刊論文


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  1. 000088241200015.pdf