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dc.contributor.authorChiou, KCen_US
dc.contributor.authorChang, FCen_US
dc.date.accessioned2014-12-08T15:45:50Z-
dc.date.available2014-12-08T15:45:50Z-
dc.date.issued2000-01-01en_US
dc.identifier.issn0887-6266en_US
dc.identifier.urihttp://hdl.handle.net/11536/30826-
dc.identifier.urihttp://dx.doi.org/10.1002/(SICI)1099-0488(20000101)38:1<23en_US
dc.description.abstractA multifunctional epoxy resin has been demonstrated to be an efficient reactive compatibilizer for the incompatible and immiscible blends of polyamide-6 (PA 6) and polybutylene terephthalate (PBT). The torque measurements give indirect evidence that the reaction between PA and PET with epoxy has an opportunity to produce an in situ formed copolymer, which can be as an effective compatibilizer to reduce and suppress the size of the disperse phase, and to greatly enhance mechanical properties of PA/PBT blends. The mechanical property improvement is more pronounced in the PA-rich blends than that in the PET-rich blends. The fracture behavior of the blend with less than 0.3 phr compatibilizer is governed by a particle pullout mechanism, whereas shear yielding is dominant in the fracture behavior of the blend with more than 0.3 phr compatibilizer. As the melt and crystallization temperatures of the base polymers are so close, either PA or PET can be regarded as a mutual nucleating agent to enhance the crystallization on the other component. The presence of compatibilizer and in situ formed copolymer in the compatibilized blends tends to interfere with the crystallization of the base polymers in various blends. (C) 2000 John Wiley & Sons, Inc.en_US
dc.language.isoen_USen_US
dc.subjectPAen_US
dc.subjectPBTen_US
dc.subjectcompatibilizeren_US
dc.subjectmorphologyen_US
dc.subjectmechanical propertiesen_US
dc.subjectcrystallizationen_US
dc.titleReactive compatibilization of polyamide-6 (PA 6)/polybutylene terephthalate (PBT) blends by a multifunctional epoxy resinen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/(SICI)1099-0488(20000101)38:1<23en_US
dc.identifier.journalJOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICSen_US
dc.citation.volume38en_US
dc.citation.issue1en_US
dc.citation.spage23en_US
dc.citation.epage33en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000084143700003-
dc.citation.woscount40-
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