標題: Synthesis of substituted poly (arylene vinylene) films by vapor deposition polymerization
作者: Li, AK
Janarthanan, N
Hsu, CS
應用化學系
Department of Applied Chemistry
公開日期: 1-Sep-2000
摘要: An efficient method for the synthesis of PPV based polymers, poly (2,5-dimethyl-1,4-phenylene vinylene) (DMe-PPV) and poly (2,5-dimethoxy-1,4-phenylene vinylene) (DOMe-PPV) were developed using 2,5-dimethyl-1,4-bis (chloromethyl) benzene and 2,5-dimethoxy 1,4-bis (chloromethyl) benzene via vapor phase pyrolysis and followed by vapor deposition polymerization. The structure of polymer films were confirmed by FT-IR, solid state NMR and elemental analysis. Thermal gravimetry analysis reveals that the precursor polymer films form a conjugated polymer after thermal conversion at 250 degrees C. The optical and electrical properties of the polymer films were investigated by UV-Vis absorption and photoluminescence spectroscopies. Electroluminescent devices were fabricated using these polymers.
URI: http://dx.doi.org/10.1007/s002890070040
http://hdl.handle.net/11536/30273
ISSN: 0170-0839
DOI: 10.1007/s002890070040
期刊: POLYMER BULLETIN
Volume: 45
Issue: 2
起始頁: 129
結束頁: 135
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