標題: Dendritic poly(ether-imide)s: synthesis, characterization, and modification
作者: Leu, CM
Shu, CF
Teng, CF
Shiea, J
應用化學系
Department of Applied Chemistry
關鍵字: dendritic poly(ether-imide)s;glass transition temperature;solubility
公開日期: 1-三月-2001
摘要: A convergent approach to the preparation of dendritic macromolecules with an aromatic ether-imide inner structure and modifiable benzyl ether chain ends is described. The structural component that constitutes the branching regions was derived from 1-(4-aminophenyl)-1,1-bis(4-hydroxyphenyl)ethane. The key steps in ether-imide dendron synthesis involve an aromatic nucleophilic displacement of an activated nitro group with phenoxide leading to the ether linkage and cyclocondensation of the amino group with 3-nitrophthalic anhydride, to give rise to the imide ring containing an activated nitro functionality. The dendritic wedges are then coupled to a polyfunctional core to complete the synthesis. The benzyl ether chain ends can be selectively removed by catalytic hydrogenolysis to produce a dendrimer with phenolic chain ends. Further modification of the chain ends is accomplished by etherfication of the phenolic groups. Structures of these dendritic poly(etherimide)s were confirmed by H-1 NMR,C-13 NMR and FTIR spectroscopy as well as by mass spectrometry. Properties such as the glass transition temperature and solubility of the dendrimer are greatly affected by the nature of the end groups. (C) 2000 Elsevier Science Ltd. All rights reserved.
URI: http://dx.doi.org/10.1016/S0032-3861(00)00611-X
http://hdl.handle.net/11536/29821
ISSN: 0032-3861
DOI: 10.1016/S0032-3861(00)00611-X
期刊: POLYMER
Volume: 42
Issue: 6
起始頁: 2339
結束頁: 2348
顯示於類別:期刊論文


文件中的檔案:

  1. 000165934200007.pdf