標題: The effect of ball-milling solvent on the decomposition properties of Ba(Pb1-xBix)O-3
作者: Chang, MC
Wu, JM
Cheng, SY
Chen, SY
材料科學與工程學系
Department of Materials Science and Engineering
關鍵字: Ba(Pb1-xBix)O-3;perovskite;solvent;decomposition
公開日期: 1-三月-2001
摘要: Ba(Pb1-xBix)O-3 compound, which exhibits perovskite structure is a superconducting material. It can be a useful material for resistor when x value equals 0. The conducting behavior of BaPbO3 is liable to be affected during aqueous processing. In contrast, the phenomenon is not found in Ba(Pb0.8Bi0.2)O-3 The milling solvents of water and ethanol have different effect on the stability of perovskite phase. The decomposition of BaPbO3 into BaCO3 and PbO2 is found when CO32- ion exists. The partial substitution of Bi3+ stabilizes the perovskite phase. The stabilization and decomposition of perovskite phase explain the resistivity change with different milling solvents. (C) 2001 Elsevier Science B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/S0254-0584(00)00400-4
http://hdl.handle.net/11536/29788
ISSN: 0254-0584
DOI: 10.1016/S0254-0584(00)00400-4
期刊: MATERIALS CHEMISTRY AND PHYSICS
Volume: 69
Issue: 1-3
起始頁: 226
結束頁: 229
顯示於類別:期刊論文


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  1. 000166822600034.pdf