標題: Heterogeneous and homogeneous catalytic oxidation by supported gamma-FeOOH in a fluidized bed reactor: Kinetic approach
作者: Chou, SS
Huang, CP
Huang, YH
環境工程研究所
Institute of Environmental Engineering
公開日期: 15-Mar-2001
摘要: Oxidation of benzoic,acid (BA) by H2O2 was performed with a never supported gamma -FeOOH catalyst in a circulating fluidized-bed reactor (CFBR).; This study focused mainly on determining the proportions of homogeneous catalysis and heterogeneous catalysis in this CFBR. Also studied herein was how pH, H2O2 concentration, and BA concentration affect the oxidation of BA. Experimental results indicate that the decomposition rate of H2O2 was proportional to its concentration and that the oxidation rate of BA depended on both H2O2 and BA concentrations. The change in the rate constant of heterogeneous catalysis by pH was described in terms of ionization fractions of surface hydroxyl group. From the mathematical deduction, we-can infer that the reaction rate associated with equivalent toF(III)OH(2)(+) is markedly higher than that with equivalent toF(III)OH. Conclusively, although heterogeneous catalysis contributes primarily to the oxidation of BA at pH 4.4-7.0, the homogeneous catalysis is of increasing importance below pH 4.4 because of the reductive dissolution of gamma -FeOOH.
URI: http://dx.doi.org/10.1021/es001129b
http://hdl.handle.net/11536/29768
ISSN: 0013-936X
DOI: 10.1021/es001129b
期刊: ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume: 35
Issue: 6
起始頁: 1247
結束頁: 1251
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