標題: Synthesis of tacamonine
作者: Ho, TL
Gorobets, E
應用化學系
Department of Applied Chemistry
關鍵字: tacamonine;mannich reaction;Beckmann fragmentation
公開日期: 10-六月-2002
摘要: Tacamonine has been synthesized in 3.2% overall yield from cyclohexanone-4-carboxylic acid ethyleneacetal. The tetrahydro-beta-carboline intermediate was submitted to a Mannich reaction to provide a bridged ring system embodying latent branches of the quinolizidine portion. The final stages included fragmentation and Grignard reaction. (C) 2002 Published by Elsevier Science Ltd.
URI: http://dx.doi.org/10.1016/S0040-4020(02)00395-2
http://hdl.handle.net/11536/28723
ISSN: 0040-4020
DOI: 10.1016/S0040-4020(02)00395-2
期刊: TETRAHEDRON
Volume: 58
Issue: 24
起始頁: 4969
結束頁: 4973
顯示於類別:期刊論文


文件中的檔案:

  1. 000176179800027.pdf