標題: Significant glass transition temperature increase based on polyhedral oligomeric silsequioxane (POSS) copolymer through hydrogen bonding
作者: Xu, HY
Kuo, SW
Chang, FC
應用化學系
Department of Applied Chemistry
公開日期: 1-七月-2002
摘要: A series of poly(vinylphenol-co-vinylpyrrolidone-co-isobutylstyryl polyhedral-oligosilsesquioxane (PVPh-co-PVP-co-POSS) copolymers were prepared by free radical copolymerization of acetoxystyrene, vinylpyrrolidone with POSS (PAS-co-PVP-co-POSS) following by selective removal of the acetyl protective group, and results in significant glass transition temperature increase. The thermal properties and hydrogen bonding of these copolymers were investigated by differential scanning calorimetry and fourier transfer infrared spectroscopy and good correlation between thermal behaviors and infrared spectroscopy results were observed.
URI: http://dx.doi.org/10.1007/s00289-002-0061-8
http://hdl.handle.net/11536/28671
ISSN: 0170-0839
DOI: 10.1007/s00289-002-0061-8
期刊: POLYMER BULLETIN
Volume: 48
Issue: 6
起始頁: 469
結束頁: 474
顯示於類別:期刊論文


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  1. 000177441800009.pdf