標題: Correlation between N 1s XPS binding energy and bond distance in metal amido, imido, and nitrido complexes
作者: Wu, JB
Lin, YF
Wang, JL
Chang, PJ
Tasi, CP
Lu, CC
Chiu, HT
Yang, YW
應用化學系
Department of Applied Chemistry
公開日期: 28-Jul-2003
摘要: Synchrotron-based X-ray photoelectron spectroscopy is used to measure N 1s binding energies of several metal amido, imido, and nitrido complexes of group 5 and 6 metals. The N 1s binding energy decreases as the formal M-N bond order increases. A simple correlation between the contraction of the M-N bond and the lowering of binding energy is also observed. This correlation supports a notion that the bonding character of a linear metal-imido linkage resembles that of a metal-nitrido linkage closely.
URI: http://hdl.handle.net/11536/27701
ISSN: 0020-1669
期刊: INORGANIC CHEMISTRY
Volume: 42
Issue: 15
起始頁: 4516
結束頁: 4518
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