標題: Imaging the pair-correlated excitation function: The F+CH4 -> HF(v ')+CH3 (nu=0) reaction
作者: Shiu, W
Lin, JJ
Liu, KP
Wu, M
Parker, DH
應用化學系
Department of Applied Chemistry
公開日期: 1-Jan-2004
摘要: The velocity map ion imaging technique was applied to measure the reaction excitation function for the first time. It was found that the "raw" excitation function was significantly distorted by the density-to-flux transformation of the title reaction. Through a systematic investigation, possible reasons for such a dramatic effect are outlined. In addition, the state-resolved, pair-correlated excitation functions and branching ratios are presented. Effects of imperfect time slicing in the time-sliced velocity imaging technique in general are also discussed. (C) 2004 American Institute of Physics.
URI: http://dx.doi.org/10.1063/1.1629668
http://hdl.handle.net/11536/27255
ISSN: 0021-9606
DOI: 10.1063/1.1629668
期刊: JOURNAL OF CHEMICAL PHYSICS
Volume: 120
Issue: 1
起始頁: 117
結束頁: 122
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