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dc.contributor.authorShiu, Wen_US
dc.contributor.authorLin, JJen_US
dc.contributor.authorLiu, KPen_US
dc.date.accessioned2019-04-03T06:37:31Z-
dc.date.available2019-04-03T06:37:31Z-
dc.date.issued2004-03-12en_US
dc.identifier.issn0031-9007en_US
dc.identifier.urihttp://dx.doi.org/10.1103/PhysRevLett.92.103201en_US
dc.identifier.urihttp://hdl.handle.net/11536/26948-
dc.description.abstractIn the course of an extensive investigation aimed at understanding the detailed mechanisms of a prototypical polyatomic reaction, several remarkable observations were uncovered. To interpret these findings, we surmise the existence of a reactive resonance in this polyatomic reaction. The reaction of concern is F+CH4-->HF+CH3, and the abnormal attributes were revealed only near the reaction threshold. The discovery of reactive resonance in a polyatomic reaction is more than just an extension from a typical atom+diatom reaction. As shown here, it holds great promise to disentangle the elusive intramolecular vibrational dynamics of transient collision complex in the critical transition-state region.en_US
dc.language.isoen_USen_US
dc.titleReactive resonance in a polyatomic reactionen_US
dc.typeArticleen_US
dc.identifier.doi10.1103/PhysRevLett.92.103201en_US
dc.identifier.journalPHYSICAL REVIEW LETTERSen_US
dc.citation.volume92en_US
dc.citation.issue10en_US
dc.citation.spage0en_US
dc.citation.epage0en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000220185600018en_US
dc.citation.woscount126en_US
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