標題: Reactive resonance in a polyatomic reaction
作者: Shiu, W
Lin, JJ
Liu, KP
應用化學系
Department of Applied Chemistry
公開日期: 12-Mar-2004
摘要: In the course of an extensive investigation aimed at understanding the detailed mechanisms of a prototypical polyatomic reaction, several remarkable observations were uncovered. To interpret these findings, we surmise the existence of a reactive resonance in this polyatomic reaction. The reaction of concern is F+CH4-->HF+CH3, and the abnormal attributes were revealed only near the reaction threshold. The discovery of reactive resonance in a polyatomic reaction is more than just an extension from a typical atom+diatom reaction. As shown here, it holds great promise to disentangle the elusive intramolecular vibrational dynamics of transient collision complex in the critical transition-state region.
URI: http://dx.doi.org/10.1103/PhysRevLett.92.103201
http://hdl.handle.net/11536/26948
ISSN: 0031-9007
DOI: 10.1103/PhysRevLett.92.103201
期刊: PHYSICAL REVIEW LETTERS
Volume: 92
Issue: 10
起始頁: 0
結束頁: 0
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