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dc.contributor.authorIwakura, Izumien_US
dc.contributor.authorYabushita, Atsushien_US
dc.contributor.authorKobayashi, Takayoshien_US
dc.date.accessioned2014-12-08T15:37:39Z-
dc.date.available2014-12-08T15:37:39Z-
dc.date.issued2011-01-07en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.cplett.2010.11.028en_US
dc.identifier.urihttp://hdl.handle.net/11536/25896-
dc.description.abstractThe vibrational populations of allyl phenyl ether were excited by a broadband visible 5-fs laser pulse by the stimulated Raman process to promote a 'non-thermal' Claisen rearrangement reaction in the electronic ground state. Analyses of the time-resolved vibrational spectra observed in the subpicosecond region has shown that the Claisen rearrangement proceeds in the following three-step pathway: (1) weakening of the C(3)O bond to generate a bis-allyl intermediate, (2) formation of the weak C(1)C(5) bond results in the generation of a six-membered structure, and (3) simultaneous processes of C(3)O breaking and C(1)C(5) formation leading to the generation of a keto-intermediate. (C) 2010 Elsevier B.V. All rights reserved.en_US
dc.language.isoen_USen_US
dc.titleNon-thermal reaction triggered by a stimulated Raman process using 5-fs laser pulses in the electronic ground state: Claisen rearrangement of allyl phenyl etheren_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.cplett.2010.11.028en_US
dc.identifier.journalCHEMICAL PHYSICS LETTERSen_US
dc.citation.volume501en_US
dc.citation.issue4-6en_US
dc.citation.spage567en_US
dc.citation.epage571en_US
dc.contributor.department電子物理學系zh_TW
dc.contributor.departmentDepartment of Electrophysicsen_US
dc.identifier.wosnumberWOS:000285829300079-
dc.citation.woscount6-
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