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dc.contributor.authorChiu, CYen_US
dc.contributor.authorChen, HWen_US
dc.contributor.authorKuo, SWen_US
dc.contributor.authorHuang, CFen_US
dc.contributor.authorChang, FCen_US
dc.date.accessioned2014-12-08T15:37:19Z-
dc.date.available2014-12-08T15:37:19Z-
dc.date.issued2004-11-02en_US
dc.identifier.issn0024-9297en_US
dc.identifier.urihttp://dx.doi.org/10.1021/ma0488156en_US
dc.identifier.urihttp://hdl.handle.net/11536/25652-
dc.description.abstractWe demonstrate that miscibility affects the ionic conductivity of ternary polymer blends of lithium perchlorate (LiClO4), poly(ethylene oxide) (PEO), and poly(E-caprolactone) (PCL). Although individually these three binary blends are fully miscible, a closed immiscibility loop exists in the ternary blend phase diagram as a result of the complicated interactions among LiClO4, PEO, and PCL. The addition of PCL suppresses the crystallization of PEO and results in higher ionic conductivity. FTIR spectroscopy studies indicate that an excess PCL content causes immiscibility, which results in PCL being excluded from the ternary blends. Consequently, the maximum ionic conductivity (6.3 x 10(-7) S cm(-1)) at ambient temperature of ternary blends having a fixed LiClO4 content (25 wt %) is at a composition of 25/60/15 (LiClO4:PEO:PCL).en_US
dc.language.isoen_USen_US
dc.titleInvestigating the effect of miscibility on the ionic conductivity of LiClO4/PEO/PCL ternary blendsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ma0488156en_US
dc.identifier.journalMACROMOLECULESen_US
dc.citation.volume37en_US
dc.citation.issue22en_US
dc.citation.spage8424en_US
dc.citation.epage8430en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000224789600037-
dc.citation.woscount32-
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