標題: Effects of Fluorinated Surfactant in Cathodic Deposition of TiO2 Films with Supercritical CO2 Emulsified Electrolyte
作者: Chang, Tso-Fu Mark
Lin, Wei-Hao
Hsu, Yung-Jung
Sato, Tatsuo
Sone, Masato
材料科學與工程學系
Department of Materials Science and Engineering
公開日期: 2014
摘要: Effect of a fluorinated surfactant, F(CF(CF3)CF2O)(3)CF(CF3)COO(CH2CH2O)CH3, in pore structure and grain size of the TiO2 films deposited cathodically was studied. Increase in pore size and decrease in grain size were observed when the fluorinated surfactant was used. When supercritical CO2 was introduced into the system, synergetic effect on increasing the pore size was observed. Also, grain coarsening was observed for the films deposited with supercritical CO2. Therefore, the fluorinated surfactant combining with supercritical CO2 demonstrated the ability to control morphology and grain size of the deposited TiO2 films at the same time. (C) 2014 The Electrochemical Society. All rights reserved.
URI: http://hdl.handle.net/11536/24055
http://dx.doi.org/10.1149/2.003404eel
ISSN: 2162-8726
DOI: 10.1149/2.003404eel
期刊: ECS ELECTROCHEMISTRY LETTERS
Volume: 3
Issue: 4
起始頁: D1
結束頁: D2
顯示於類別:期刊論文


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  1. 000333069400004.pdf