標題: Transient Infrared Absorption Spectra of Reaction Intermediates Detected with a Step-scan Fourier-transform Infrared Spectrometer
作者: Huang, Yu-Hsuan
Chen, Jin-Dah
Hsu, Kuo-Hsiang
Chu, Li-Kang
Lee, Yuan-Pern
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
關鍵字: Step-scan;Fourier-transform infrared spectroscopy;Transient absorption;FTIR;Free radicals
公開日期: 1-Jan-2014
摘要: Our group has utilized a step-scan FTIR spectrometer operating in the absorption mode to characterize transient species in chemical reactions upon photo-irradiation of gaseous mixtures in a multipass White cell. The operational temporal resolution is typically 1-10 s with spectral resolution 0.1-4 cm(-1), depending on conditions. The acquisition of both ac- and dc-coupled signals enables an extraction of minute changes in the large background signal to attain a typical detectable absorbance variation greater than 1 x 10(-4). By consideration of reaction mechanisms and comparison of vibrational wavenumbers, IR intensities, and rotational contours predicted with theoretical calculations, we have assigned IR absorption bands of many important atmospheric free radicals and unstable species including their conformers, such as ClCO, ClSO, ClCS, ClCOOH, CH3SO2, CH3SOO, CH3OSO, CH3SO, CH3OO, CH3C(O)OO, CH2OO C6H5CO, C6H5SO2, and C6H5C(O)OO. The advantages and limitations of this technique to perform spectral and kinetic investigations of transient species in chemical reactions are discussed.
URI: http://dx.doi.org/10.1002/jccs.201300415
http://hdl.handle.net/11536/23879
ISSN: 0009-4536
DOI: 10.1002/jccs.201300415
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 61
Issue: 1
起始頁: 47
結束頁: 58
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