標題: Intramolecular Interactions of a Phenyl/Perfluorophenyl Pair in the Formation of Supramolecular Nanofibers and Hydrogels
作者: Hsu, Shu-Min
Lin, Yu-Chun
Chang, Jui-Wen
Liu, Yu-Hao
Lin, Hsin-Chieh
材料科學與工程學系
Department of Materials Science and Engineering
關鍵字: hydrogels;nanofibers;noncovalent interactions;self-assembly;supramolecular chemistry
公開日期: 10-二月-2014
摘要: A new system for the incorporation of a phenyl/perfluorophenyl pair in the structure of a peptide hydrogelator was developed. The strategy is based on the idea that the integration of an end-capped perfluorophenyl group and a phenylalanine with a phenyl moiety in the side chain forms an intramolecular phenyl/perfluorophenyl pair, which can be used to promote the formation of the supramolecular nanofibers and hydrogels. This work illustrates the importance of structure-hydrogelation relationship and provides new insights into the design of self-assembly nanobiomaterials.
URI: http://dx.doi.org/10.1002/anie.201307500
http://hdl.handle.net/11536/23790
ISSN: 1433-7851
DOI: 10.1002/anie.201307500
期刊: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume: 53
Issue: 7
起始頁: 1921
結束頁: 1927
顯示於類別:期刊論文


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  1. 000330680400032.pdf