標題: Infrared spectra of free radicals and protonated species produced in para-hydrogen matrices
作者: Bahou, Mohammed
Das, Prasanta
Lee, Yu-Fang
Wu, Yu-Jong
Lee, Yuan-Pern
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 2014
摘要: The quantum solid para-hydrogen (p-H-2) has emerged as a new host for matrix isolation experiments. Among several unique characteristics, the diminished cage effect enables the possibility of producing free radicals via either photolysis in situ or bimolecular reactions of molecules with atoms or free radicals that are produced in situ from their precursors upon photo-irradiation. Many free radicals that are unlikely to be produced in noble-gas matrices can be produced readily in solid p-H-2. In addition, protonated species can be produced upon electron bombardment of p-H-2 containing a small proportion of the precursor during deposition. The application of this novel technique to generate protonated polycyclic aromatic hydrocarbons (PAH) and their neutral counterparts demonstrates its superiority over other methods. The technique of using p-H-2 as a matrix host has opened up many possibilities for the preparation of free radicals and unstable species and their spectral characterization. Many new areas of applications and fundamental understanding concerning the p-H-2 matrix await further exploration.
URI: http://hdl.handle.net/11536/23629
http://dx.doi.org/10.1039/c3cp54184c
ISSN: 1463-9076
DOI: 10.1039/c3cp54184c
期刊: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume: 16
Issue: 6
起始頁: 2200
結束頁: 2210
Appears in Collections:Articles