標題: The Elusive Three-Coordinate Dicationic Hydrido Boron Complex
作者: Chen, Wen-Ching
Lee, Ching-Yu
Lin, Bo-Chao
Hsu, Yu-Chen
Shen, Jiun-Shian
Hsu, Chao-Ping
Yap, Glenn P. A.
Ong, Tiow-Gan
應用化學系
Department of Applied Chemistry
公開日期: 22-Jan-2014
摘要: The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.
URI: http://dx.doi.org/10.1021/ja4120852
http://hdl.handle.net/11536/23590
ISSN: 0002-7863
DOI: 10.1021/ja4120852
期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume: 136
Issue: 3
起始頁: 914
結束頁: 917
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