標題: Electrophoretic fabrication and pseudocapacitive properties of graphene/manganese oxide/carbon nanotube nanocomposites
作者: Hung, Chung Jung
Lin, Pang
Tseng, Tseung Yuen
材料科學與工程學系
電子工程學系及電子研究所
Department of Materials Science and Engineering
Department of Electronics Engineering and Institute of Electronics
關鍵字: Pseudocapacitor;Electrophoretic deposition (EPD);Nanocomposites;Manganese oxide;Graphene;Energy storage
公開日期: 1-十二月-2013
摘要: Hybrid nanocomposites provided a synergistic improvement on electrochemical performance and stability for pseudocapacitor. Designed graphene/carbon nanotubes (CNTs)/MnO2 nanocomposites with CNTs electrode (in short, GMC + C) with highly nanoporous framework surface structure are fabricated by a modified electrophoretic deposition (EPD) method. Scanning electron microscopy and transmission electron microscopy analysis demonstrate that the flake-like MnO2 thickness (about less than 10 nm) and uniformly distributed on the porous graphene/CNTs framework. X-ray diffraction shows the formation of birnessite-type MnO2. Pseudocapacitances of the GMC + C electrode calculated by cyclic voltammetry having different scan rates of 5, 20, 50, 100, and 300 mV s(-1) exhibit high specific capacitances of 481, 436, 413, 398, and 372 F g, respectively. Sodium ion diffusion coefficients of the GMC + C electrode show a higher intercalation value of 3.647 x 10(-8) cm(2) s(-1) and deintercalation value of 2.899 x 10(-8) cm(2) s(-1) using chronoamperometry. Moreover, the GMC + C electrode maintains a high specific capacitance of 346 F g(-1), and is about 833% of the initial capacitance after 15,000 charge/discharge cycles. The designed hybrid GMC + C nanocomposites pseudocapacitor electrode using EPD route with the high specific capacitance, fast reaction rate, and high stability, exhibits high potential for practical applications. (C) 2013 Elsevier B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jpowsour.2013.06.055
http://hdl.handle.net/11536/22925
ISSN: 0378-7753
DOI: 10.1016/j.jpowsour.2013.06.055
期刊: JOURNAL OF POWER SOURCES
Volume: 243
Issue: 
起始頁: 594
結束頁: 602
顯示於類別:期刊論文


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