標題: Formal Synthesis of 3-Deoxy-D-manno-Octulosonic Acid (KDO) and 3-Deoxy-D-arabino-2-heptulosonic Acid (DAH)
作者: Pradhan, Tapan Kumar
Lin, Chun Cheng
Mong, Kwok Kong Tony
應用化學系
Department of Applied Chemistry
關鍵字: carbohydrates;Wittig;Corey-Fuchs;cyclization
公開日期: 1-一月-2013
摘要: Practical synthetic routes to 3-deoxy-D-manno-octulo-sonic acid (KDO) and 3-deoxy-D-arabino-2-heptulosonic acid (DAH) from common sugar substrates are reported. Chain homologation of the sugar substrates was accomplished by Wittig olefination and Corey-Fuchs alkynylation. A new cyclization strategy was investigated to access the desired pyranosyl isomer of the KDO target.
URI: http://dx.doi.org/10.1055/s-0032-1317932
http://hdl.handle.net/11536/21295
ISSN: 0936-5214
DOI: 10.1055/s-0032-1317932
期刊: SYNLETT
Volume: 
Issue: 2
起始頁: 219
結束頁: 222
顯示於類別:期刊論文


文件中的檔案:

  1. 000314697700019.pdf