標題: Eu2+-Activated Sr8ZnSc(PO4)(7): A Novel Near-Ultraviolet Converting Yellow-Emitting Phosphor for White Light-Emitting Diodes
作者: Huang, Chien-Hao
Chiu, Yi-Chen
Yeh, Yao-Tsung
Chan, Ting-Shan
Chen, Teng-Ming
應用化學系
Department of Applied Chemistry
關鍵字: Sr8ZnSc(PO4)(7);yellow-emitting;Eu2+;NUV;white LED;photoluminescence
公開日期: 1-十二月-2012
摘要: The crystal structure of Eu2+-activated Sr8ZnSc(PO4)(7):Eu2+ phosphor was refined and determined from XRD profiles by the Rietveld refinement method using a synchrotron light source. This phosphor crystallizes in the monoclinic structure with the I2/a space group. The SZSP:xEu(2+) phosphors showed a broad yellow emission band centered at 511 and 571 nm depending on the concentration of Eu2+, and the composition-optimized concentration of Eu2+ in the Sr8ZnSc(PO4)(7):Eu2+ phosphor was determined to be 2 mol %. The estimated crystal-field splitting and CIE chromaticity coordinates of Sr8ZnSc(PO4)(7):xEu(2+) (x = 0.001-0.05 mol) were 20181-20983 cm(-1) and (0.3835, 0.5074) to (0.4221, 0.5012), respectively, and the emission band showed a redshift from 547 to 571 nm with increasing Eu2+ concentration. The nonradiative transitions between the Eu2+ ions in the Sr8ZnSc(PO4)(7) host were attributable to dipole-dipole interactions, and the critical distance was approximately 19.8 angstrom. The combination of a 400 nm NUV chip with a blend of Sr8ZnSc(PO4)(7):0.02Eu(2+) and BAM:Eu2+ phosphors (light converters) gave high color rendering indices between 79.38 and 92.88, correlated color temperatures between 4325 and 7937 K, and tuned CIE chromaticity coordinates in the range (0.381, 0.435) to (0.294, 0.310), respectively, depending on the SZSP:0.02Eu(2+)/BAM:Eu2+ weight ratio. These results suggest that the Sr8ZnSc(PO4)(7):0.02Eu(2+)/BAM:Eu2+ phosphor blend has potential applications in white NUV LEDs.
URI: http://dx.doi.org/10.1021/am302014e
http://hdl.handle.net/11536/20922
ISSN: 1944-8244
DOI: 10.1021/am302014e
期刊: ACS APPLIED MATERIALS & INTERFACES
Volume: 4
Issue: 12
起始頁: 6661
結束頁: 6667
顯示於類別:期刊論文


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  1. 000313149800037.pdf