標題: Formation of size-tunable dandelion-like hierarchical rutile titania nanospheres for dye-sensitized solar cells
作者: Lan, Chi-Ming
Liu, Shang-En
Shiu, Jia-Wei
Hu, Jyun-Yu
Lin, Meng-Hung
Diau, Eric Wei-Guang
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 2013
摘要: A sol-gel method with a modified solvent comprising of three simple steps under low-temperature conditions was used to synthesize mono-disperse rutile TiO2 nanospheres with dandelion-like hierarchical morphology (DHRS) as a light-scattering layer for dye-sensitized solar cells (DSSC). 1,2-Ethanediol (ED) served as a key retardation agent in the second step at 25 degrees C to slow the hydrolysis and condensation of the TiCl4 aqueous solution prepared in the first step at 0 degrees C; the subsequent nucleation of a rutile type phase occurred homogeneously in the third step at 70 degrees C to generate the rutile TiO2 nanospheres with highly uniform sizes. The spherical sizes of DHRS were well controlled with the volume ratios of the ED-water solvent mixture in the second step, for which the DHRS of diameter 650-200 nm were produced from the solvent system containing 5-25% ED. A detailed mechanism is presented to rationalize the formation of nanospheres of uniform size in six steps: 1) hydration and hydrolysis, 2) hydrolysis and retardation, 3) hydrolysis and condensation, 4) homogeneous nucleation, 5) aggregation and growth of rod-like crystals and 6) DHRS formation. The DSSC device with a scattering layer made of DHRS (size similar to 300 nm) performed comparably to that with a scattering layer made of a commercially available TiO2 paste, making this nano-material a cost-effective alternative for future DSSC commercialization.
URI: http://hdl.handle.net/11536/20813
http://dx.doi.org/10.1039/c2ra22807f
ISSN: 2046-2069
DOI: 10.1039/c2ra22807f
期刊: RSC ADVANCES
Volume: 3
Issue: 2
起始頁: 559
結束頁: 565
顯示於類別:期刊論文


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  1. 000312196600036.pdf