標題: Fourier-transform microwave spectroscopy of the H-2-HCN complex
作者: Ishiguro, Masazumi
Harada, Kensuke
Tanaka, Keiichi
Tanaka, Takehiko
Sumiyoshi, Yoshihiro
Endo, Yasuki
應用化學系
Department of Applied Chemistry
公開日期: 3-十二月-2012
摘要: Fourier-transform microwave spectroscopy was applied to observe the J = 1-0 rotational transition of the H-2-HCN complex for both the ortho-and para-H-2 species to obtain improved molecular constants by an analysis combined with the millimeter-wave data. It was confirmed that the para-and ortho-H-2 species have different configurations: namely H-2 is attached to the H end of HCN in the former, while to the N end in the latter. For the ortho-H-2 species, the hyperfine splitting due to the magnetic interaction between the hydrogen nuclei was observed to give the nuclear spin-spin coupling constant d(H) = 54.6(38) kHz. (C) 2012 Elsevier B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.cplett.2012.10.012
http://hdl.handle.net/11536/20585
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2012.10.012
期刊: CHEMICAL PHYSICS LETTERS
Volume: 554
Issue: 
起始頁: 33
結束頁: 36
顯示於類別:期刊論文


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