Title: A new supramolecular POSS electroluminescent material
Authors: Chu, Yu-Lin
Cheng, Chih-Chia
Chen, Ya-Ping
Yen, Ying-Chieh
Chang, Feng-Chih
應用化學系
Department of Applied Chemistry
Issue Date: 2012
Abstract: A new polyhedral oligomeric silsesquioxane (POSS) core star-like supramolecular blue-light electroluminescent material, 4-uracilbutyl-1-methylpyrene ether (U-PY)/octakis[dimethyl(N-(6-acetamidopyridin- 2 yl))siloxy] silsesquioxane (ODAP-POSS) has been synthesized. This U-PY/ODAP-POSS contains eight pyrene chromophore arms formed through complementary uracil-diamidopyridine (U-DAP) pairs and exhibits high quantum efficiencies and good solution processing properties. The photoluminescence spectra of U-PY/ODAP-POSS (50/50) reveal that the color is stable after heating the sample at 150 degrees C for 1 h, in contrast, the pyrene/ODAP-POSS (50/50) shows significant thermal quenching. An electroluminescence (EL) device based on U-PY/ODAP-POSS exhibits higher maximum brightness and higher luminance efficiency relative to that of the U-PY. In addition, U-PY/ODAP-POSS also behaves as an effective dopant that enhances energy transfer from itself to MEH-PPV. The U-PY/ODAP-POSS-doped MEH-PPV blends exhibit high luminance efficiency, 1.45 times greater than MEH-PPV.
URI: http://hdl.handle.net/11536/16199
ISSN: 0959-9428
Journal: JOURNAL OF MATERIALS CHEMISTRY
Volume: 22
Issue: 18
End Page: 9285
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