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dc.contributor.authorHuang, Yao-Jhengen_US
dc.contributor.authorYe, Yun-Shengen_US
dc.contributor.authorSyu, Yu-Jyuanen_US
dc.contributor.authorHwang, Bing-Joeen_US
dc.contributor.authorChang, Feng-Chihen_US
dc.date.accessioned2014-12-08T15:22:33Z-
dc.date.available2014-12-08T15:22:33Z-
dc.date.issued2012-06-15en_US
dc.identifier.issn0378-7753en_US
dc.identifier.urihttp://hdl.handle.net/11536/15950-
dc.description.abstractSulfonated polytriazole-clay (SFTA-clay) nanocomposites are successfully prepared by in situ polymerization of SPTA using click chemistry in the presence of propargyl-functionality modified clay. The clay layers are exfoliated and well dispersed within the SPTA matrix resulting in improvements in thermal stability, mechanical strength, methanol permeability, water retention, ion channel size, and ionic cluster distribution. The SPTA-clay nanocomposite membranes with small amounts of clay in the SPTA matrices possess higher selectivity's; defined as the ratio of proton conductivity to methanol permeability, and thus have potential as proton exchange membranes (PEMs) in direct methanol fuel cells (DMFCs). (C) 2012 Elsevier B.V. All rights reserved.en_US
dc.language.isoen_USen_US
dc.subjectClayen_US
dc.subjectIn situ polymerizationen_US
dc.subjectSulfonated polytriazoleen_US
dc.subjectClick chemistryen_US
dc.subjectProton exchange membraneen_US
dc.titleSynthesis and characterization of sulfonated polytriazole-clay proton exchange membrane by in situ polymerization and click reaction for direct methanol fuel cellsen_US
dc.typeArticleen_US
dc.identifier.journalJOURNAL OF POWER SOURCESen_US
dc.citation.volume208en_US
dc.citation.issueen_US
dc.citation.epage144en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000303286500016-
dc.citation.woscount12-
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