標題: Controlled synthesis and luminescent properties of monodispersed PEI-modified YVO4:Bi3+,Eu3+ nanocrystals by a facile hydrothermal process
作者: Chen, Yi-Chin
Wu, Yun-Chen
Wang, De-Yin
Chen, Teng-Ming
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 2012
摘要: A series of water-soluble YVO4:Bi3+, Eu3+ nanocrystals, with surfaces functionalized by a branch polyethylenimine (BPEI) polymer, have been synthesized via a one-pot hydrothermal method. It was found that the particle size and crystal morphology could be efficiently controlled by different reaction temperatures, pH values and molecular weights of the BPEI polymer. The surface modification of the nanocrystals was characterized using Fourier transform infrared spectroscopy (FT-IR). The highly crystalline YVO4:Bi3+, Eu3+ nanoparticles, with an average diameter of 20 nm, can be dispersed in water due to the presence of amino ligands. When conjugated with biomolecules, the YVO4:Bi3+, Eu3+ nanocrystals retain their strong red emission, peaking at 619 nm under near-ultraviolet (n-UV) excitation. The results indicate that YVO4:Bi3+, Eu3+ nanocrystals can serve as a promising candidate for biological imaging, and immunoassay applications.
URI: http://hdl.handle.net/11536/15861
http://dx.doi.org/10.1039/c2jm30756a
ISSN: 0959-9428
DOI: 10.1039/c2jm30756a
期刊: JOURNAL OF MATERIALS CHEMISTRY
Volume: 22
Issue: 16
起始頁: 7961
結束頁: 7969
Appears in Collections:Articles


Files in This Item:

  1. 000302026100046.pdf