Title: Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser
Authors: Abe, Manabu
Iwakura, Izumi
Yabushita, Atushi
Yagi, Shingo
Liu, Jun
Okamura, Kotaro
Kobayashi, Takayoshi
電子物理學系
Department of Electrophysics
Issue Date: 27-Feb-2012
Abstract: The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative. (C) 2012 Elsevier B. V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.cplett.2012.01.024
http://hdl.handle.net/11536/15621
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2012.01.024
Journal: CHEMICAL PHYSICS LETTERS
Volume: 527
Issue: 
Begin Page: 79
End Page: 83
Appears in Collections:Articles


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