標題: Concise Synthesis of Yashabushidiol A and (+/-)-Diospongin A
作者: Ho, Tse-Lok
Tang, Bin
Ma, Guohua
Xu, Pengfei
應用化學系
Department of Applied Chemistry
關鍵字: (2SR,4RS)-pentane-1,2,4,5-tetraol;Dithiane alkylation;Desulfurization;meso-1,7-Diarylheptanoids;Cyclization
公開日期: 1-三月-2012
摘要: Synthesis of (+/-)-diospongin A has been achieved from the (2SR,4RS)-pentane-1,2,4,5-tetraol in six steps. An intermediate has also been converted into yashabushidiol A. This work features a desymmetric cyclization and reduction of a meso-1,7-diarylheptanoid precursor to furnish the desired cis-2,6-disubstituted tetrahydropyran.
URI: http://dx.doi.org/10.1002/jccs.201100664
http://hdl.handle.net/11536/15578
ISSN: 0009-4536
DOI: 10.1002/jccs.201100664
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 59
Issue: 3
起始頁: 455
結束頁: 458
顯示於類別:期刊論文


文件中的檔案:

  1. 000301092800028.pdf