標題: Synthesis of a Furanosyl-pyranone Derivative Related to the Tri-O-heterocyclic Core of Herbicidins
作者: Hsu, Ching-Yun
Lee, I-Chi
Lico, Larry S.
Uang, Biing-Jiun
Hung, Shang-Cheng
應用化學系
Department of Applied Chemistry
關鍵字: Benzylidene acetal;Cycloaddition;Danishefsky-type diene;Herbicidins;Regioselectivity
公開日期: 1-三月-2012
摘要: A new compound that is structurally related to the undecose ring structure of herbicidins has been prepared. The synthesis of this novel furanosyl-pyranone derivative was made possible through the regioselective reductive ring-opening of a 3,5-O-benzylidene-D-xylofuranose and the hetero-Diels-Alder reaction of an aldehyde and a Danishefsky-type diene. The highly functionalized pyranone derivative can be a useful precursor for the synthesis of herbicidins.
URI: http://dx.doi.org/10.1002/jccs.201100744
http://hdl.handle.net/11536/15577
ISSN: 0009-4536
DOI: 10.1002/jccs.201100744
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 59
Issue: 3
起始頁: 421
結束頁: 425
顯示於類別:期刊論文


文件中的檔案:

  1. 000301092800023.pdf