標題: Synthesis of poly(4-vinylphenol) (PVPh) and polyhedral oligomeric silsesquioxanes-poly(4-vinylphenol) (POSS-PVPh) with low surface energy and their surface properties
作者: Liao, Chun-Hsiung
Chien, Fu-Ming
Chen, Chen-Ming
Liu, Lung-Chang
Chung, Ming-Hua
Chang, Feng-Chih
應用化學系
Department of Applied Chemistry
關鍵字: Polymers;Thin films;Chemical synthesis;Surface properties
公開日期: 15-十二月-2011
摘要: In this paper, we have synthesized poly(4-vinylphenol) (PVPh) and polyhedral oligomeric silsesquioxanes-poly(4-vinylphenol) (POSS-PVPh) with low surface energies and investigated their surface properties. Experimental results reveal that the surface properties of PVPh and POSS-PVPh can be manipulated with the length of PVPh segment and POSS contents, respectively, resulting in the variation of intermolecular hydrogen bonding interactions. In addition, the surface energies of PVPh after thermal treatment of 180 degrees C for 24 h can be less than 20 mJ m(-2) and those of POSS-PVPh without thermal treatment can be less than 25 mJ m-2 while those of poly(tetrafluoroethylene)(PTFE) are 22 mJ m(-2). (C) 2011 Elsevier B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.matchemphys.2011.09.053
http://hdl.handle.net/11536/15359
ISSN: 0254-0584
DOI: 10.1016/j.matchemphys.2011.09.053
期刊: MATERIALS CHEMISTRY AND PHYSICS
Volume: 131
Issue: 1-2
起始頁: 343
結束頁: 347
顯示於類別:期刊論文


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