Title: Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); Syntheses and X-ray crystal structures of N Cr(OBu(t))(3) and N Mo(OSiMe(3))(3)(py)
Authors: Chiu, HT
Chen, YP
Chuang, SH
Jen, JS
Lee, GH
Peng, SM
Department of Applied Chemistry
Issue Date: 21-Jan-1996
Abstract: Mononuclear nitrido complexes of Cr and Mo, N=Cr(OBu(t))(3) and N=Mo(OSiMe(3))(3)(py), are synthesized; the chromium complex has an idealized C-3v symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N-Cr distance is 1.538(5) Angstrom while the average N-Mo distance is 1.627 Angstrom.
URI: http://dx.doi.org/10.1039/cc9960000139
ISSN: 1359-7345
DOI: 10.1039/cc9960000139
Issue: 2
Begin Page: 139
End Page: 140
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  1. A1996UG03600013.pdf