標題: Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); Syntheses and X-ray crystal structures of N Cr(OBu(t))(3) and N Mo(OSiMe(3))(3)(py)
作者: Chiu, HT
Chen, YP
Chuang, SH
Jen, JS
Lee, GH
Peng, SM
應用化學系
Department of Applied Chemistry
公開日期: 21-一月-1996
摘要: Mononuclear nitrido complexes of Cr and Mo, N=Cr(OBu(t))(3) and N=Mo(OSiMe(3))(3)(py), are synthesized; the chromium complex has an idealized C-3v symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N-Cr distance is 1.538(5) Angstrom while the average N-Mo distance is 1.627 Angstrom.
URI: http://dx.doi.org/10.1039/cc9960000139
http://hdl.handle.net/11536/1498
ISSN: 1359-7345
DOI: 10.1039/cc9960000139
期刊: CHEMICAL COMMUNICATIONS
Volume: 
Issue: 2
起始頁: 139
結束頁: 140
顯示於類別:期刊論文


文件中的檔案:

  1. A1996UG03600013.pdf