標題: A study on blends of liquid crystalline copolyesters with polycarbonate .2. Transesterification control
作者: Wei, KH
Su, KF
交大名義發表
材料科學與工程學系
National Chiao Tung University
Department of Materials Science and Engineering
公開日期: 31-一月-1996
摘要: The inhibited and catalyzed ester exchange (transesterification) during melt blending of poly(bisphenol-A carbonate) (PC) and liquid crystalline poly(oxybenzoate-co-ethylene terephthalate) (POB-PET 40/60; P46) was investigated with differential scanning calorimetry. It was found that the ester exchange between P46 and PC was effectively inhibited for a 20% P46 blend at 240 degrees C, as further confirmed by nuclear magnetic spectroscopy. When the blending temperature and P46 concentration increased, only the transesterification between the PET segment in P46 and PC took place under inhibition. The morphology of the blends was analyzed with scanning electron microscopy and displayed a disconnected interface between P46 and PC under inhibition. Conversely, the transesterification took place between the POB segment in P46 and PC when a catalyst was added. (C) 1996 John Wiley & Sons, Inc.
URI: http://hdl.handle.net/11536/1493
ISSN: 0021-8995
期刊: JOURNAL OF APPLIED POLYMER SCIENCE
Volume: 59
Issue: 5
起始頁: 787
結束頁: 796
顯示於類別:期刊論文


文件中的檔案:

  1. A1996TQ34500005.pdf