標題: Layer-Dependent Dielectric Function of Wafer-Scale 2D MoS2
作者: Song, Baokun
Gu, Honggang
Fang, Mingsheng
Chen, Xiuguo
Jiang, Hao
Wang, Renyan
Zhai, Tianyou
Ho, Yen-Teng
Liu, Shiyuan
材料科學與工程學系
Department of Materials Science and Engineering
關鍵字: layer-dependent dielectric function;spectroscopic ellipsometry;two-step method;wafer-scale 2D MoS2
公開日期: 18-Jan-2019
摘要: Wafer-scale, high-quality, and layer-controlled 2D MoS2 films on c-sapphire are synthesized by an innovative two-step method. The dielectric functions of MoS2 ranging from the monolayer to the bulk are investigated by spectroscopic ellipsometry over an ultra-broadband (0.73-6.42 eV). Up to five critical points (CPs) in the dielectric function spectra are precisely distinguished by CP analysis, and their physical origins are identified in the band structures with the help of first-principles calculations. Results demonstrate that the center energies of these CPs exhibit intriguing layer dependency, which are interpreted by the intrinsic layer-dependent transitions in MoS2. Specially, the change in the imaginary part of the dielectric functions versus the thickness exhibits a "W" like curve, and the two valley bottoms appear at about four-layer and 10-layer respectively. These complex fluctuations are attributed to the alternating domination of the decreasing excitonic effect, the increasing joint density of states, and the mass density increase in relative thick MoS2 samples.
URI: http://dx.doi.org/10.1002/adom.201801250
http://hdl.handle.net/11536/148738
ISSN: 2195-1071
DOI: 10.1002/adom.201801250
期刊: ADVANCED OPTICAL MATERIALS
Volume: 7
Appears in Collections:Articles