標題: Relative Isomer Abundance of Fullerenes and Carbon Nanotubes Correlates with Kinetic Stability
作者: Fedorov, A. S.
Fedorov, D. A.
Kuzubov, A. A.
Avramov, P. V.
Nishimura, Y.
Irle, S.
Witek, Henryk A.
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 20-十月-2011
摘要: A methodology to evaluate the kinetic stability of carbon nanostructures is presented based on the assumption of the independent and random nature of thermal vibrations. The kinetic stability is directly correlated to the cleavage probability for the weakest bond of a given nanostructure. The application of the presented method to fullerenes and carbon nanotubes yields clear correlation to their experimentally observed relative isomer abundances. The general and simple formulation of the method ensures its applicability to other nanostructures for which formation is controlled by kinetic factors.
URI: http://dx.doi.org/10.1103/PhysRevLett.107.175506
http://hdl.handle.net/11536/14728
ISSN: 0031-9007
DOI: 10.1103/PhysRevLett.107.175506
期刊: PHYSICAL REVIEW LETTERS
Volume: 107
Issue: 17
結束頁: 
顯示於類別:期刊論文