標題: Desymmetrization of 2,4,5,6-Tetra-O-benzyl-D-myo-inositol for the Synthesis of Mycothiol
作者: Chung, Chuan-Chung
Zulueta, Medel Manuel L.
Padiyar, Laxmansingh T.
Hung, Shang-Cheng
應用化學系
Department of Applied Chemistry
公開日期: 21-十月-2011
摘要: An efficient chemical synthesis of mycothiol Involving the regioselective ketopinyl desymmetrization of 2,4,5,6-tetrabenzylated D-myo-inositol as the key step Is described. Together with a highly alpha-stereoselective D-glucosaminylation, the whole procedure was accomplished in eight steps with an overall yield of 40%.
URI: http://dx.doi.org/10.1021/ol202218n
http://hdl.handle.net/11536/14727
ISSN: 1523-7060
DOI: 10.1021/ol202218n
期刊: ORGANIC LETTERS
Volume: 13
Issue: 20
起始頁: 5496
結束頁: 5499
顯示於類別:期刊論文


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  1. 000295817100022.pdf