標題: Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry
作者: Goseki, Raita
Ito, Shotaro
Matsuo, Yuri
Higashihara, Tomoya
Hirao, Akira
應用化學系
Department of Applied Chemistry
關鍵字: living anionic polymerization;linking chemistry;-star polymer;high generation dendrimer-like hyperbranched polymer;exactly defined graft polymers;multiblock polymers;iterative methodology;benzyl bromide;-phenylacrylate
公開日期: 1-Oct-2017
摘要: This article reviews the development of a novel all-around iterative methodology combining living anionic polymerization with specially designed linking chemistry for macromolecular architecture syntheses. The methodology is designed in such a way that the same reaction site is always regenerated after the polymer chain is introduced in each reaction sequence, and this polymer chain introduction and regeneration of the same reaction site sequence is repeatable. Accordingly, the polymer chain can be successively and, in principle, limitlessly introduced to construct macromolecular architectures. With this iterative methodology, a variety of synthetically difficult macromolecular architectures, i.e., multicomponent -star polymers, high generation dendrimer-like hyperbranched polymers, exactly defined graft polymers, and multiblock polymers having more than three blocks, were successfully synthesized.
URI: http://dx.doi.org/10.3390/polym9100470
http://hdl.handle.net/11536/144066
ISSN: 2073-4360
DOI: 10.3390/polym9100470
期刊: POLYMERS
Volume: 9
Issue: 10
起始頁: 0
結束頁: 0
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