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dc.contributor.authorSingh, Ravinderen_US
dc.contributor.authorWu, Hsin-Yenen_US
dc.contributor.authorDwivedi, Atul Kumaren_US
dc.contributor.authorSingh, Ashutoshen_US
dc.contributor.authorLin, Chien-Minen_US
dc.contributor.authorRaghunath, Putikamen_US
dc.contributor.authorLin, Ming-Changen_US
dc.contributor.authorWu, Tung-Kungen_US
dc.contributor.authorWei, Kung-Hwaen_US
dc.contributor.authorLin, Hong-Cheuen_US
dc.date.accessioned2018-08-21T05:52:45Z-
dc.date.available2018-08-21T05:52:45Z-
dc.date.issued2017-10-14en_US
dc.identifier.issn2050-7526en_US
dc.identifier.urihttp://dx.doi.org/10.1039/c7tc03071aen_US
dc.identifier.urihttp://hdl.handle.net/11536/143916-
dc.description.abstractA novel photo-switchable polymer P-PHT containing diarylethene (DAE) and tetraphenylethene (TPE) moieties and a triazole linker in the repeating unit was synthesized to study the aggregation-induced emission (AIE) behaviour of TPE with both the open and closed forms of DAE in P-PHT with high water contents. The photo-switching phenomena of DAE (from open to closed forms under UV-irradiation) in P-PHT were prominent in organic solvent (THF), high water contents (at 90% H2O) and acidic conditions. Upon UV-irradiation of P-PHT at 90% water content, the AIE of TPE was completely quenched via an energy transfer event from TPE to cyclized DAE. Interestingly, the rare monomeric emission of TPE was first discovered by the photo-cyclization of DAE in P-PHT compared with the AIE behaviour of TPE with the open form of DAE in P-PHT with AIE favourable conditions of high water content (90% H2O) and acidic conditions.en_US
dc.language.isoen_USen_US
dc.titleMonomeric and aggregation emissions of tetraphenylethene in a photo-switchable polymer controlled by cyclization of diarylethene and solvent conditionsen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c7tc03071aen_US
dc.identifier.journalJOURNAL OF MATERIALS CHEMISTRY Cen_US
dc.citation.volume5en_US
dc.citation.spage9952en_US
dc.citation.epage9962en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.department生物科技學系zh_TW
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.contributor.departmentDepartment of Biological Science and Technologyen_US
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000412827000016en_US
Appears in Collections:Articles