標題: Two-color resonant four-wave mixing spectroscopy of highly predissociated levels in the (A)over-tilde(2)A(1) state of CH3S
作者: Liu, CP
Reid, SA
Lee, YP
應用化學系
Department of Applied Chemistry
公開日期: 22-三月-2005
摘要: We report results of two-color resonant four-wave mixing experiments on highly predissociated levels of the methylthio (or thiomethoxy) radical CH3S in its first excited electronic state A (2)A(1). Following photolysis of jet-cooled dimethyl disulfide at 248 nm, the spectra were measured with a hole-burning scheme in which the probe laser excited specific rotational transitions in band 3(3). The spectral simplification afforded by the two-color method allows accurate determination of line positions and homogeneous linewidths, which are reported for the C-S stretching states 3(v)(v=3-7) and combination states 1(1)3(v)(v=0-2), 2(1)3(v)(v=3-6), and 1(1)2(1)3(v)(v=0,1) involving the symmetric CH3 stretching (nu(1)) mode and the CH3 umbrella (nu(2)) mode. The spectra show pronounced mode specificity, as the homogeneous linewidth of levels with similar energies varies up to two orders of magnitude; nu(3) is clearly a promoting mode for dissociation. Derived vibrational wave numbers omega(1)('), omega(2)('), and omega(3)(') of the A state agree satisfactorily with ab initio predictions.
URI: http://dx.doi.org/10.1063/1.1867333
http://hdl.handle.net/11536/13888
ISSN: 0021-9606
DOI: 10.1063/1.1867333
期刊: JOURNAL OF CHEMICAL PHYSICS
Volume: 122
Issue: 12
結束頁: 
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  1. 000228287900022.pdf