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dc.contributor.authorCheng, Chih-Chiaen_US
dc.contributor.authorChang, Feng-Chihen_US
dc.contributor.authorDai, Shenghong A.en_US
dc.contributor.authorLin, Yu-Lien_US
dc.contributor.authorLee, Duu-Jongen_US
dc.date.accessioned2019-04-03T06:36:21Z-
dc.date.available2019-04-03T06:36:21Z-
dc.date.issued2015-01-01en_US
dc.identifier.issn2046-2069en_US
dc.identifier.urihttp://dx.doi.org/10.1039/c5ra19708ben_US
dc.identifier.urihttp://hdl.handle.net/11536/129454-
dc.description.abstractComplementary nucleobase-functionalized polymers, a combination of base-pair interactions and a blend of two different polymers, can be used for efficient construction of supramolecular polymer networks; these materials exhibit tunable mechanical properties, rapid thermo-responsiveness and self-healing behavior making them highly attractive for a wide range of potential applications. Herein, a multi-uracil functionalized polyhedral oligomeric silsesquioxane (POSS-U) and adenine end-capped three-arm polycaprolactone oligomer (PCL-A) have been successfully developed and show high complementary ability in both solution and the solid state owing to reversible uracil-adenine (U-A)-induced physical cross-linking. The POSS-U/PCL-A blend system demonstrates that physically crosslinked films can be readily tailored to provide the desired mechanical properties and rapidly reprocessed after damage under mild temperature conditions. Importantly, these films can also spontaneously self-heal at room temperature as an autonomously repairing material, without the need for external intervention. Thus, this new system provides a potential route toward the design and fabrication of next-generation self-healing polymers.en_US
dc.language.isoen_USen_US
dc.titleBio-complementary supramolecular polymers with effective self-healing functionalityen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c5ra19708ben_US
dc.identifier.journalRSC ADVANCESen_US
dc.citation.volume5en_US
dc.citation.issue110en_US
dc.citation.spage90466en_US
dc.citation.epage90472en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000364053500028en_US
dc.citation.woscount10en_US
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