標題: Effect of the transition metal on the synthesis of quaternary sulfides MPb8In17S34 (M = Cu, Ag, Au)
作者: Wang, KC
Lee, CS
應用化學系
Department of Applied Chemistry
公開日期: 20-Feb-2006
摘要: Quaternary sulfides MPb8In17S34 (M = Cu, Ag, Au) were synthesized at 1123 K from their elements in stoichiometric ratios. These compounds crystallize in monoclinic space group P2(1)/m. The crystal structures feature combinations of (2)(infinity)[InS2] (NaCl111-type) and (2)(infinity)[MPb2In3S6] (NaCl100-type) slabs. These compounds are semiconductors with band gaps near 1.3 eV.
URI: http://dx.doi.org/10.1021/ic051447h
http://hdl.handle.net/11536/12619
ISSN: 0020-1669
DOI: 10.1021/ic051447h
期刊: INORGANIC CHEMISTRY
Volume: 45
Issue: 4
起始頁: 1415
結束頁: 1417
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