標題: The B (3)Sigma(-) state of the SO radical
作者: Liu, Ching-Ping
Elliott, Nicola L.
Western, Colin M.
Lee, Yuan-Pern
Colin, Reginald
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
關鍵字: SO;radicals;DFWM;perturbations;electronic spectroscopy
公開日期: 1-Aug-2006
摘要: Spectra of the B-3 Sigma(-) - X (3)Sigma(-) transition in SO above the first dissociation limit are recorded using degenerate four wave mixing. These spectra are combined with earlier work involving laser induced fluorescence, absorption spectra and Fourier transform emission spectra, to enable a rotational analysis and deperturbation of vibrational levels of the B state up to v' = 16. Numerous perturbations were noted within the B (3)Sigma(-) state, and the origin of these is discussed. In a number of cases, these perturbations can be attributed to interactions with specific other electronic states of SO, such as A (3)Pi, C (3)Pi, d (1)Pi, and A '' (3)Pi(+). (c) 2006 Elsevier Inc. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jms.2006.05.005
http://hdl.handle.net/11536/11971
ISSN: 0022-2852
DOI: 10.1016/j.jms.2006.05.005
期刊: JOURNAL OF MOLECULAR SPECTROSCOPY
Volume: 238
Issue: 2
起始頁: 213
結束頁: 223
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